不同淀粉原料的疏水改性及其性质研究
CSTR:
作者:
作者单位:

作者简介:

张志衡(1990-),男,硕士,研究方向为淀粉改性、碳水化合物功能材料 通讯作者:高群玉(1965-),女,博士,教授,主要从事谷物科学、淀粉改性及碳水化合物科学的教学与科研工作

通讯作者:

中图分类号:

基金项目:

广东省部产学研(2012B091100291);东莞市产学研合作项目(2014509111106)


Modification of the Hydrophobicity of Different Starches and Their Properties
Author:
Affiliation:

Fund Project:

  • 摘要
  • |
  • 图/表
  • |
  • 访问统计
  • |
  • 参考文献
  • |
  • 相似文献
  • |
  • 引证文献
  • |
  • 资源附件
  • |
  • 文章评论
    摘要:

    本文研究了不同添加量的辛烯基琥珀酸酐(OSA)、Al3+以及不同pH值在改性过程中对玉米淀粉、木薯淀粉和马铃薯淀粉休止角、活化指数、接触角、分散性、和偏光特性的影响。实验表明,随着OSA、Al3+添加量和交联过程中pH值的增加,玉米淀粉和木薯淀粉的休止角呈现出先减少后增加的特征,而只有pH值的变化对马铃薯淀粉的休止角产生了比较明显的影响;改性后,三中淀粉的接触角均大于90°,证明淀粉疏水性得到显著提高;同时,在活化指数试验中,木薯淀粉和马铃薯淀粉的活化指数可以达到0.95;液体石蜡中的分散性测试表明,玉米淀粉的分散性最好,其次是木薯淀粉,马铃薯淀粉的分散性最差,而改性后淀粉的分散性较原淀粉并未出现明显变化;最后,通过观察同等光强条件下淀粉的偏光特性,发现改性后淀粉颗粒出现偏光十字变弱、表面阴影增加的情况。

    Abstract:

    Various properties including the angle of repose, activation index, contact angle, dispersibility, and polarized light property of different types of starch (corn starch, tapioca starch, and potato starch) were analyzed in this study. Additionally, the effects of different pH conditions and different concentrations of added octenyl succinic anhydride (OSA) and Al3+ were investigated. The results showed that the angles of repose of corn and tapioca starch presented an initial decrease, followed by an increase, with higher pH values and increasing concentrations of added OSA and Al3+. Variation of pH value showed an obvious effect on angle of repose in case of potato starch only. Modification caused the contact angles of different types of starch to increase to >90°, indicating a significant improvement in the hydrophobic property of all three kinds of starch. The activation index for both, tapioca and potato starch reached a value of 0.95. The results of the dispersibility test in liquid paraffin showed highest dispersibility for corn starch, followed by tapioca starch, whereas potato starch showed lowest dispersibility. However, the dispersibility of modified starch did not change significantly as compared to that of native starch. Finally, the properties of starch under polarized light of the same intensity showed that the birefringence of modified starch granules was weaker and the shadow areas were larger.

    参考文献
    相似文献
    引证文献
引用本文

张志衡,高群玉.不同淀粉原料的疏水改性及其性质研究[J].现代食品科技,2016,32(2):73-78.

复制
相关视频

分享
文章指标
  • 点击次数:
  • 下载次数:
  • HTML阅读次数:
  • 引用次数:
历史
  • 收稿日期:2015-04-24
  • 最后修改日期:
  • 录用日期:
  • 在线发布日期: 2016-03-15
  • 出版日期:
文章二维码
×
因办公室装修,期间暂时无法接听电话,如有事请QQ或邮件联系。信息咨询:QQ: 2553003667稿件处理1:QQ: 1542354573稿件处理2:QQ: 2195608851 财务咨询:QQ: 1347040116 Email:mfood@scut.edu.cn、mfood@foxmail.com